Search results for "Nanogels synthesi"

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Numerical Simulation of the Kinetics of Radical Decay in Single-Pulse High-Energy Electron-Irradiated Polymer Aqueous Solutions

2019

A new method for the numerical simulation of the radiation chemistry of aqueous polymer solutions is introduced. The method makes use of a deterministic approach combining the conventional homogeneous radiation chemistry of water with the chemistry of polymer radicals and other macromolecular species. The method is applied on single-pulse irradiations of aqueous polymer solutions. The speciation of macromolecular species accounts for the variations in the number of alkyl radicals per chain, molecular weight, and number of internal loops (as a consequence of an intramolecular radical-radical combination). In the simulations, the initial polymer molecular weight, polymer concentration, and do…

chemistry.chemical_classificationAqueous solutionNanogels synthesi010304 chemical physicsComputer simulationKineticsPOLY(ETHYLENE OXIDE); SYNTHETIC-POLYMERS; RADIOLYSIS; NANOGELS; DEGRADATIONSingle pulseElectronPolymerRadiation chemistry010402 general chemistry01 natural sciencesradiation chemistry0104 chemical sciencesCondensed Matter::Soft Condensed MatterchemistryChemical physicsnumerical simulation0103 physical sciencesebeam irradiationSettore CHIM/07 - Fondamenti Chimici Delle TecnologieIrradiationPhysical and Theoretical ChemistryThe Journal of Physical Chemistry A
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